Publications
Found results
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2024. Coordination-induced bond weakening and small molecule activation by low-valent titanium complexes. Dalton Transactions. 53:2413-2441.
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2023. Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening. Inorganic Chemistry. 62(12)
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2023. Mechanistic study for efficient nitrogen fixation. Nature Synthesis. 2(7)
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2022. Ammonia Solvation vs Aqueous Solvation of Samarium Diiodide. A Theoretical and Experimental Approach to Understanding Bond Activation Upon Coordination to Sm(II). The Journal of Organic Chemistry. 87(3):1689-1697.
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2022. Coordination-Induced Bond Weakening. Chemical Reviews. 122(16)
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2020. Proton donor effects on the reactivity of SmI2. Experimental and theoretical studies on methanol solvation vs. aqueous solvation. Dalton Transactions. 49(23):7902.
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2020. Titanocenes as photoredox catalysts using green-light irradiation. Angewandte Chemie, International Edition. 59(24):9359.
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2019. Contrasting Effect of Additives on Photoinduced Reactions of SmI2. Chemistry A European Journal. 25
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2019. Coordination-induced O-H bond weakening in Sm(II)-water complexes. Dalton Transactions. 48(43):16147.
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2019. Experimental and Theoretical Studies on the Aqueous Solvation and Reactivity of SmCl2 and Comparison with SmBr2 and SmI2. Inorganic Chemistry. 58(20):13932.
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2019. Mechanistic Study and Development of Catalytic Reactions of Sm(II). Journal of the American Chemical Society . 141(7):3216.
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2018. Cp2TiX Complexes for Sustainable Catalysis in Single Electron Steps. Chem. Eur. J. (24)
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2018. Experimental and Theoretical Studies on the Implications of Halide-Dependent Aqueous Solvation of Sm(II). Journal of the American Chemical Society . 140(48)
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2018. The Interplay between Substrate and Proton Donor Coordination in Reductions of Carbonyls by SmI2-Water Through Proton-Coupled Electron-Transfer. Journal of the American Chemical Society .
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2018. Kinetic Solvent Effects in the Reduction of Alkyl Halides by {Sm[N(SiMe3)2]2(THF)2}. Organometallic Chemistry. (857)
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2017. Aza versus Oxophilicity of SmI2: A Break of a Paradigm. Chemistry European Journal . (23):17077.
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2017. Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system. Catalysis Science and Technology .
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2017. Reversibility of Ketone Reduction by SmI2–Water and Formation of Organosamarium Intermediates. Organometallics.
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2017. Secondary Amides as Hydrogen Atom Transfer Promoters for Reactions of Samarium Diiodide. Organic Letters. 19(1):3.
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2016. ADAM17 Inhibitors Attenuate Corneal Epithelial Detachment Induced by Mustard Exposure.. Investigative Opthamology and Visual Science. 57(4):11.
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2016. High-Affinity Proton Donors Promote Proton-Coupled Electron Transfer by Samarium Diiodide. Angewandte Chemie International Edition. 128(20):3.
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2016. Highly Active Titanocene Catalysts for Epoxide Hydrosilylation: Synthesis, Theory, Kinetics, EPR Spectroscopy. Angewandte Chemie International Edition.
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2016. Origin and prediction of free-solution interaction studies performed label-free. Proceedings of the National Academy of Sciences of the United States of America. 133(12)
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2016. Proton-Coupled Electron Transfer in the Reduction of Carbonyls by Samarium Diiodie-Water Complexes. Journal of the American Chemical Society.
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2016. Tuning the redox properties of the titanocene(iii)/(iv)-couple for atom-economical catalysis in single electron steps. Dalton Transactions. 45(2):4.
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2015. Allylsamarium Bromide-Mediated Cascade Cyclization of Homoallylic Esters. Synthesis of 2-(2-Hydroxyalkyl)cyclopropanols and 2-(2-Hydroxyethyl)bicyclo[2.1.1]hexan-1-ols. J. Org. Chem.. 80(1):52-61.
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2015. Cationic Titanocene(III) Complexes for Catalysis in Single-Electron Steps. Angewandte Chemie. 2015(54):7003-7009.
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2015. Ligand functionalization as a deactivation pathway in a fac-Ir(ppy)3-mediated radical addition. Chemical Science. 2015(1):537-541.
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2015. Mechanistic Study of Silver-Catalyzed Decarboxylative Fluorination. The Journal of Organic Chemistry. 80(11):5834–5841.
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2015. Mechanistic study of the samarium diiodide—N,N-dimethyl-2-aminoethanol reducing system. Tetrahedron Letters. 56(23):3212-3215.
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2015. Mechanistic Study of the Titanocene(III)-Catalyzed Radical Arylation of Epoxides. Chemistry - A European Journal. 21(1):280-288.
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2015. Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2–Water Complexes. Journal of the American Chemical Society. 137(35):11526-11531.
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2015. Tuning the Redox Properties of the Titanocene(III)/(IV)-Couple for Atom-Economical Catalysis in Single Electron Steps. Dalton Transactions.
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2014. Solvent-Dependent Substrate Reduction by {Sm[N(SiMe3)2]2(THF)2}. An Alternative Approach for Accelerating the Rate of Substrate Reduction by Sm(II). Journal of Organic Chemistry. 79(20):9443.
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2014. Substituent Effects and Supramolecular Interactions of Titanocene(III) Chloride: Implications for Catalysis in Single Electron Steps. Journal of the American Chemical Society. 136(4):1671.
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2013. Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds. Beilstein Journal of Organic Chemistry. 9:8.
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2013. Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction. Journal of Visual Chemistry.
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2013. Substrate-Directable Electron Transfer Reactions. Dramatic Rate Enhancement in the Chemoselective Reduction of Cyclic Esters Using SmI2-H2O: Mechanism, Scope, and Synthetic Utility. Journal of the American Chemical Society. 135(42):3.
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2013. Uncovering the Mechanism of the Ag(I)/Persulfate-Catalyzed Cross-Coupling Reaction of Arylboronic Acids and Heteroarenes. Journal of the American Chemical Society. 135(12):4675.
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2012. Back-Scattering Interferometry: An Ultrasensitive Method for the Unperturbed Detection of Acetylcholinesterase-Inhibitor Interactions. Angewandte Chemie, International Edition. 51(44):4.
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2011. Backscattering Interferometry: A Versatile Platform for the Study of Free-Solution vs. Surface Immobilized Hybridization. Chemistry - A European Journal. 6
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2011. Backscattering Interferometry: an alternative approach for the study of hydrgen bonding interactions in organic solvents. Organic Letters. 13
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2011. Catalytic Ni(II) in Reactions of SmI2: Sm(II)- or Ni(0)-Based Chemistry? Journal of the American Chemical Society. 133
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2011. A convenient pathway to Sm(II)-mediated chemistry in acetonitrile. Organic & Biomolecular Chemistry. 9
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2011. Investigation of Anticholinergic and Non-steroidal Anti-inflammatory Prodrugs which Reduce Chemically-induced Skin Inflammation. Journal of Applied Toxicology. 292
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2011. On the Nature of Oxidative Coupling of Lithium Enolates. Journal of the American Chemical Society. 133
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2010. Dynamic Ligand Exhange in Reactions of Samarium Diiodide. Org. Lett.. 12
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2010. Efficient protein renaturation using tunable hemifluorinated anionic surfactants as additives. Chem. Commun.. 46
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2010. Mechanistic Complexity in Organo-SOMO Activation. Angew. Chem., Int. Ed.. 49
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2010. Peripheral Site Acetylcholinesterase Inhibitors Targeting Both Inflammation and Cholinergic Dysfunction. Bioorg. Med. Chem. Lett.. 20
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2010. Selective Monovalent Cation Association and Exchange around Keplerate Polyoxometalate Macroanions in Dilute Aqueous Solution. Langmuir. 26
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2010. Uncovering the Mechanistic Role of HMPA in the Samarium Barbier Reaction. J. Am. Chem. Soc.. 132
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2009. Ce(IV)-Based Synthesis of Tetrasubstituted Pyrazoles. Synlett.
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2009. Generation of Triarylamine Radical Cations Through Reaction of Triarylamines with Cu(II) in Acetonitrile. A Kinetic Investigation. J. Phys. Chem.. 113
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2009. Solvent-Dependent Oxidative Coupling of 1-Aryl-1,3-dicarbonyls and Styrene. Tetrahedron. 65
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2009. Studies on the Mechanism, Selectivity, and Synthetic Utility of Lactone Reduction Using SmI2 and H2O. J. Am. Chem. Soc.. 131
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2009. Synthesis of γ-substituted Ketones via the Ce(IV)-mediated Oxidative Coupling of Cyclobutanols and Inorganic Halides. Tetrahedron Lett.. 50
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2008. Generation of Sm(II) Reductants Using High Intensity Ultrasound. Eur. J. Inorg. Chem..
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2007. An Efficient and General Approach to β-Functionalized Ketones. Org. Lett.. 9(1323)
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2007. Mechanistic Role of Proton Donor Coordination in Reactions of Samarium Diiodide. Angew. Chem.. 46
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2007. Mechanistic Studies of Ce(IV)-mediated Oxidation of 1,3-Dicarbonyls: Solvent-Dependent Behavior of Radical Cation Intermediates. J. Org. Chem.. 72
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2007. Solvation Controlled Luminescence of Sm(II) Complexes. Angew. Chem.. 46
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2006. A Convenient One-Pot Synthesis of Spirocyclic Pyrido[1,2-a]indole Derivatives from 3-(2-Bromoethyl)indole. Synlett.
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2006. Mechanistic Evidence for Intermolecular Radical Carbonyl Additions Promoted by Samarium Diiodide. J. Am. Chem. Soc.. 128
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2006. Mild Conversion of β-diketones to Carboxylic Acids by CAN. J. Org. Chem.. 71
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2006. Samarium(II)-Based Reductants. Handbook on the Physics and Chemistry of Rare Earths. 36
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2005. Chelation-Controlled Diastereoselective Reduction of α-Fluoroketones. J. Am. Chem. Soc.. 127
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2005. Cyclic Aromatic Oligoamides as Highly Selective Receptors for the Guanidinium Ion. Chem. Comm..
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2005. Exploring SmBr2, SmI2, and YbI2 Mediated Reactions assisted by Microwave Irradiation. Chem. Eur. J.. 11
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2005. Photoinduced Electron Transfer Reactions by SmI2 in THF: Luminescence Quenching Studies and Mechanistic Investigations.. Chem. Eur. J.. 11
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2005. Reduction of β-hydroxyketones by SmI2/H2O/Amine. Org. Lett.. 7
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2005. The Role of Water in SmI2-Mediated Reductions of Alkyl Halides. J. Am. Chem. Soc.. 127
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2004. A Polymer-Supported Phosphoramide as a Lewis Base-Catalyst for the Catalytic Aldol Reaction. Eur. J. Org. Chem..
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2004. The Role of Ligand Displacement in Sm(II)-HMPA Based Reductions. J. Am. Chem. Soc.. 126
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2004. The Role of Proton Donors in SmI2 Mediated Ketone Reduction: New Mechanistic Insights. J. Am. Chem. Soc.. 126
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2004. Solvent Dependent Chemoselectivities in Additions of β-Carbonyl Imines to Allyl Trimethylsilane Using CTAN. J. Org Chem.. 69
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2004. Solvent Dependent Diastereoselectivities in Reductions of β-Hydroxyketones by SmI2. Org. Lett.. 6
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2003. Mechanistic Investigation of Substrate Oxidation by Ce(IV) Reagents in Acetonitrile. J. Org. Chem.. 68
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2003. Rapid SmI2 Mediated Reductions of Alkyl Halides and Electrochemical Properties of SmI2/H2O/Amine. J. Org. Chem.. 68
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2003. Reduction and Reductive Coupling of Imines by Sm(II)-Based Reagents. Tetrahedron. 59
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2003. Solvent Dependent Chemoselectivities in Ce(IV) Mediated Oxidative Coupling Reactions. Org. Lett.. 5
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2002. Investigation of the [Sm{N(SiMe3)2}2] Reducing System in THF. Rate and Mechanistic Studies. J. Am. Chem. Soc.. 124
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2002. Mechanistic Study of β-Substituent Effects on the Mechanism of Ketone Reduction by SmI2. J. Am. Chem. Soc.. 124
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2002. Molecular Clips that Undergo Self-Sorting and Heterochiral Aggregation. Angew. Chem.. 41
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2002. A Non-Covalent Approach to Anti-Parallel β-Sheet Formation. J. Am. Chem. Soc.. 124
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2002. Protein Micelles from Lipoxygenase 3. Am. Chem. Soc.. 124
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2002. Reduction of Alkyl Halides and Ketones by SmI2 and Sm(II)-HMPA Complexes. Rate and Mechanistic Studies. J. Am. Chem. Soc.. 124
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2001. Human Rad52 Protein Has Extreme Thermal Stability. Biochemistry. 40
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2001. Influence of HMPA on the Reducing Power and Reactivity of SmBr2. Org. Lett.. 3
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2001. Sequence Specificity of Hydrogen-Bonded Molecular Duplexes. J. Org. Chem.. 66
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2000. Electrochemical Investigation of the Solvolytic Properties of Ethylammonium Nitrate (EAN). Electroanalysis. 12
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2000. Guest and Subunit Exchange in Self-Assembled Ionophores. Org. Lett.. 2
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2000. Highly Organized Spherical Hosts That Bind Organic Guest in Aqueous Solution with Micromolar Affinity: Microcalorimetry Studies. Chem. Eur. J.. 6
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2000. A Highly Stable, Six-Hydrogen Bonded Molecular Duplex. J. Am. Chem. Soc.. 122
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2000. SmI2-Mediated Nitrile Aldol Reaction. Tetrahedron Lett.. 41